(I looked at the DOS port, but Apple II has the same rooms.)
I've marked the most interesting unused rooms with yellow.
As you can see, one of the things I found is that room 20 of level 13 still contains an old version of room 20 of level 12.
Mechner copied the entire level 12 to level 13, then he didn't use room 20 in level 13, and he later modified room 20 of level 12 to be more difficult.
So, I discovered a bit of PoP development history.

Three collage images attached below.